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CasNo: 104-38-1
Molecular Formula: C10H14O4
Appearance: white to off-white crystalline powder or flakes
Synthesis Reference(s) |
Tetrahedron Letters, 29, p. 163, 1988 DOI: 10.1016/S0040-4039(00)80042-8 |
Flammability and Explosibility |
Nonflammable |
InChI:InChI=1/C10H14O4/c11-5-7-13-9-1-2-10(4-3-9)14-8-6-12/h1-4,11-12H,5-8H2
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oxirane
hydroquinone
1,4-bis(2-hydroxyethoxy)benzene
Conditions | Yield |
---|---|
hydroquinone;
With
1,1'-bis-(diphenylphosphino)ferrocene;
In
diethylene glycol dimethyl ether;
at 100 ℃;
Autoclave;
Inert atmosphere;
oxirane;
In
diethylene glycol dimethyl ether;
at 130 - 135 ℃;
for 4h;
Solvent;
Temperature;
|
99.3% |
anion exchange resin A (Cl-type);
In
2-methoxy-ethanol; toluene;
at 100 ℃;
for 6h;
|
73% |
anion exchange resin A (Cl-type);
In
2-methoxy-ethanol;
at 100 ℃;
for 4.5h;
|
69 %Chromat. |
hydroquinone
2-chloro-ethanol
1,4-bis(2-hydroxyethoxy)benzene
Conditions | Yield |
---|---|
hydroquinone;
With
sodium hydroxide;
In
water;
for 2h;
Inert atmosphere;
Reflux;
2-chloro-ethanol;
In
water;
for 40h;
Reflux;
Inert atmosphere;
|
74% |
With
sodium hydroxide;
In
water;
for 24h;
Heating;
|
60% |
With
sodium hydroxide;
Inert atmosphere;
|
|
With
sodium hydroxide;
at 130 ℃;
|
|
With
sodium hydroxide; calcium carbonate;
|
|
With
sodium hydroxide;
In
ethanol;
|
|
With
potassium carbonate; lithium bromide;
In
acetonitrile;
at 90 ℃;
for 72h;
|
[1,3]-dioxolan-2-one
hydroquinone
2-chloro-ethanol
sodium 4-hydroxybenzen-1-olate
1,4-bis-(2-ethoxycarbonyloxy-ethoxy)-benzene
1,4-bis-(2-acetoxy-ethoxy)-benzene
1,4-bis-(2-methacryloyloxy-ethoxy)-benzene
1,6-bis-{2-[4-(2-hydroxy-ethoxy)-phenoxy]-ethoxycarbonylamino}-hexane